Switching the selectivity of a polyglycerol dendrimer monomolecularly imprinted with d-(−)-fructose

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Switching the selectivity of a polyglycerol dendrimer monomolecularly imprinted with D-(-)-fructose.

A polyglycerol dendrimer unimolecularly imprinted with D-(-)-fructose (Fru) was synthesized. The dendrimer formed adducts with several monosaccharides, Fru, D-(+)-galactose, D-(+)-glucose, D-(+)-mannose, and methyl-alpha-D-mannopyranoside (MMan), by removal of four water molecules. The dendrimer preferred Fru in the absence of N,N,N',N'-tetramethylmethylenediamine (TMDAM), whereas it preferred ...

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ژورنال

عنوان ژورنال: Tetrahedron Letters

سال: 2009

ISSN: 0040-4039

DOI: 10.1016/j.tetlet.2009.02.168